Seminars on Fouling and Coking in Refinery and Petrochemical Plants
 
 
 
Introduction: Fouling and Coking in Plant Operations
  • Photographs of 18 plant process fouling problems
  • Cost of fouling to plant operations
  • Plant safety related to fouling and coking
  • Investigating plant fouling and mitigation
  • Laboratory measurements of fouling(using tube-in shell exchanger)
  • Analytical methods used in fouling investigations
Fouling in Crude oil Processing
  • Causes of fouling in crude oil processing
  • Fouling caused by organic mechanisms
  • Fouling caused by inorganic materials
  • Asphaltenes role in crude oil fouling
  • Blending of crude oils and their effect on fouling
  • Characterization of plant fouling deposits and their relationship to fouling
  • Monitoring crude oil fouling using fouling analyzers
  • Mitigation of fouling (Blending, asphaltene control, antifoulants, equipment metallurgy)
Fouling in Hydrotreater Process
  • Characterization of hydrotreater feed and their heavy fractions
  • Measurement of dissolved oxygen (laboratory and on-site)
  • Reactivity of various hydrocarbons to air oxidation
  • Causes of hydrotreater fouling
  • Thermal fouling testing of hydrotreater feedstock (tube-in-shell exchanger)
  • Characterization of plant fouling deposits and their relationship to fouling
  • Laboratory polymerization of hydrotreater feedstock
  • Effect of various organic sulfur compounds on naphtha fouling
  • Effect of particulates on fouling
  • Characterization of fouling deposits
  • Effect of hydrotreating on fouling of hydrocarbons
  • Chemical changes occurring during hydrotreating

Fouling in Delayed Coker Process
  • Characterization of coker feedstock
  • Coking of petroleum resid and their fractions
  • Laboratory measurements of coker furnace tube fouling
  • Coker feed asphaltene and their effect on coking
  • Processing of coker feed blends(Slop oils, ROSE bottom, aromatics, used lube oil)
  • Characterization of foulant coke from delayed coker
  • De-coking of foulant coke (air and steam air)
  • Potential methods for mitigating delayed coker fouling
  • Preparation and characterization of petrocoke
Fouling in Visbreaker Process
  • Chemical reactions in Visbreaking process
  • Laboratory testing of Visbreaker feed fouling
  • Coke formation in Visbreaker furnace
  • Effect of feed asphaltene on conversion
  • Incompatibility of Visbreaker tar
  • Mitigation of furnace coking and tar incompatibility
Fouling of Cat Cracking Process
  • Introduction
  • Characterization of FCC slurry and its residue
  • Thermal polymerization of FCC slurry
  • Thermal fouling of FCC slurry (using tube-in-shell exchanger)
  • Mechanism of FCC slurry fouling
  • Effect of fractionator temperature on slurry exchanger fouling
  • Relationship of FCCU feed and slurry
  • Correlation of FFC slurry characteristics to fouling
  • Mitigation of FCC unit fouling
Fouling in Steam Cracking Process
  • Fouling of steam cracker light end
  • Mechanism of coke formation in furnace tubes
  • Characterization of furnace foulant coke deposits
  • Carburization of furnace metal tubes
  • Effect of temperature on foulant coke microstructure
  • Laboratory de-coking of furnace coke deposits
  • Mitigation of fouling in fractionator and furnace tubes
  • Composition of steam cracker tar
  • Effect of temperature on steam cracked tar stability
  • Potential uses of steam cracker tar
Fouling in Petrochemical Plants
  • Measurement of dissolved oxygen and its effect on fouling
  • Fouling in mixed C4 processing
  • Fouling in butadiene and isoprene processing
  • Fouling in ethylene dichloride plants
  • Fouling in styrene production
  • Fouling of pyrolysis gasoline
  • Peroxide and popcorn polymer formation
  • Fouling of ethyl benzene
  • Fouling of acrylates
Fouling in Gas Compressor Operations
  • Causes of gas compressor fouling
  • Composition of gases from various processes
  • Characteristics of compressor fouling deposits
  • Gas/liquid separators and their effect on compressor fouling
  • Laboratory investigation of compressor fouling
  • Mitigation of compressor fouling
Fouling of Filters and Mitigation
  • Characterization of deposits from filter fouling
  • Measurements of feedstock fouling
  • Solubility of filter deposits in organic solvents
  • Development of filter cleaning procedure
Fouling of Utility Boilers
  • Residual fuel oil production
  • Potential problems caused by residual fuel oil
  • Incompatibility of residual fuel oil
  • Role of asphaltene in burner tip fouling
  • Laboratory measurements of residual fuel oil stability
  • Mitigation of utility boiler fouling by chemicals
Fouling of Acid Gas Scrubbing Process
  • Problems in acid gas scrubbing
  • Cause(s) of fouling in acid gas scrubbing
  • Air oxidation of acetaldehyde
  • Fouling mitigation in amine and caustic extraction by antifoulants
Fouling in Lube Oil / Furfural Extraction Process
  • Problems in furfural extraction units
  • Role of dissolved oxygen in furfural oxidation
  • Effect of furfural oxidation on acid and polymer formation
  • Laboratory measurement of furfural fouling
  • Characteristics of fouling deposits
  • Mitigation of fouling in lube / furfural plants
Other Fouling Technology
  • Fouling of distillate fuel
  • Fouling of heating oils
  • Fouling of benzene scrubbing units
  • Fouling in NGL processing plants
  • Asphaltenes: Characterization, solubility, incompatibility and fouling
  • Fouling of H-oil process
  • Co-processing of used lube oil and petroleum resid